Syntheses and crystal structures of zinc(II) complexes with three kinds of piperidine carboxylic acids

Yoshie Inomata; Kazuhiko Sasaki; Hidekazu Umehara; F. Scott Howell

doi:10.1016/S0020-1693(00)00361-3

Syntheses and crystal structures of zinc(II) complexes with three kinds of piperidine carboxylic acids

Yoshie Inomata
, Kazuhiko Sasaki
, Hidekazu Umehara
, F. Scott Howell

Sophia University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Zinc(II) complexes with DL-piperidine-2-carboxylic acid (Hpipe-2), DL-piperidine 3-carboxylic acid (Hpipe-3), and piperidine-4-carboxylic acid (Hpipe-4):ZnCl₂(Hpipe 2)₂, ZnCl₂(Hpipe-3)₂(H₂O)₃, and ZnCl₂(Hpipe-4) have been prepared and characterized by means of IR spectra and thermal analysis. The crystal structures of [ZnCl₂(Hpipe-3)₂]·3H₂O and [ZnCl₂(Hpipe-4)] have been determined by X-ray diffraction. The crystal of [ZnCl₂(Hpipe-3)₂]·3H₂O is monoclinic with the space group P2₁/c. The zinc atom is in a tetrahedral geometry, ligated by two carboxylato oxygen atoms and two chlorine atoms. The crystal of [ZnCl₂(Hpipe-4)] is triclinic with space group P1̄. This complex consists of a binuclear molecule bridged by two carboxylato oxygen atoms. The zinc atom is in a tetrahedral geometry ligated by two carboxylato oxygen atoms and two chlorine atoms.

Original language	English
Pages (from-to)	95-99
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	313
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(00)00361-3
Publication status	Published - 26 Feb 2001
Externally published	Yes

Keywords

Binuclear complexes
Crystal structures
Piperidine carboxylic acid
Zinc(II) complexes

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10.1016/S0020-1693(00)00361-3

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@article{151126610a414c4cbe9c2ae2e1f5d954,

title = "Syntheses and crystal structures of zinc(II) complexes with three kinds of piperidine carboxylic acids",

abstract = "Zinc(II) complexes with DL-piperidine-2-carboxylic acid (Hpipe-2), DL-piperidine 3-carboxylic acid (Hpipe-3), and piperidine-4-carboxylic acid (Hpipe-4):ZnCl2(Hpipe 2)2, ZnCl2(Hpipe-3)2(H2O)3, and ZnCl2(Hpipe-4) have been prepared and characterized by means of IR spectra and thermal analysis. The crystal structures of [ZnCl2(Hpipe-3)2]·3H2O and [ZnCl2(Hpipe-4)] have been determined by X-ray diffraction. The crystal of [ZnCl2(Hpipe-3)2]·3H2O is monoclinic with the space group P21/c. The zinc atom is in a tetrahedral geometry, ligated by two carboxylato oxygen atoms and two chlorine atoms. The crystal of [ZnCl2(Hpipe-4)] is triclinic with space group P{\=1}. This complex consists of a binuclear molecule bridged by two carboxylato oxygen atoms. The zinc atom is in a tetrahedral geometry ligated by two carboxylato oxygen atoms and two chlorine atoms.",

keywords = "Binuclear complexes, Crystal structures, Piperidine carboxylic acid, Zinc(II) complexes",

author = "Yoshie Inomata and Kazuhiko Sasaki and Hidekazu Umehara and Howell, \{F. Scott\}",

year = "2001",

month = feb,

day = "26",

doi = "10.1016/S0020-1693(00)00361-3",

language = "English",

volume = "313",

pages = "95--99",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Syntheses and crystal structures of zinc(II) complexes with three kinds of piperidine carboxylic acids

AU - Inomata, Yoshie

AU - Sasaki, Kazuhiko

AU - Umehara, Hidekazu

AU - Howell, F. Scott

PY - 2001/2/26

Y1 - 2001/2/26

N2 - Zinc(II) complexes with DL-piperidine-2-carboxylic acid (Hpipe-2), DL-piperidine 3-carboxylic acid (Hpipe-3), and piperidine-4-carboxylic acid (Hpipe-4):ZnCl2(Hpipe 2)2, ZnCl2(Hpipe-3)2(H2O)3, and ZnCl2(Hpipe-4) have been prepared and characterized by means of IR spectra and thermal analysis. The crystal structures of [ZnCl2(Hpipe-3)2]·3H2O and [ZnCl2(Hpipe-4)] have been determined by X-ray diffraction. The crystal of [ZnCl2(Hpipe-3)2]·3H2O is monoclinic with the space group P21/c. The zinc atom is in a tetrahedral geometry, ligated by two carboxylato oxygen atoms and two chlorine atoms. The crystal of [ZnCl2(Hpipe-4)] is triclinic with space group P1̄. This complex consists of a binuclear molecule bridged by two carboxylato oxygen atoms. The zinc atom is in a tetrahedral geometry ligated by two carboxylato oxygen atoms and two chlorine atoms.

AB - Zinc(II) complexes with DL-piperidine-2-carboxylic acid (Hpipe-2), DL-piperidine 3-carboxylic acid (Hpipe-3), and piperidine-4-carboxylic acid (Hpipe-4):ZnCl2(Hpipe 2)2, ZnCl2(Hpipe-3)2(H2O)3, and ZnCl2(Hpipe-4) have been prepared and characterized by means of IR spectra and thermal analysis. The crystal structures of [ZnCl2(Hpipe-3)2]·3H2O and [ZnCl2(Hpipe-4)] have been determined by X-ray diffraction. The crystal of [ZnCl2(Hpipe-3)2]·3H2O is monoclinic with the space group P21/c. The zinc atom is in a tetrahedral geometry, ligated by two carboxylato oxygen atoms and two chlorine atoms. The crystal of [ZnCl2(Hpipe-4)] is triclinic with space group P1̄. This complex consists of a binuclear molecule bridged by two carboxylato oxygen atoms. The zinc atom is in a tetrahedral geometry ligated by two carboxylato oxygen atoms and two chlorine atoms.

KW - Binuclear complexes

KW - Crystal structures

KW - Piperidine carboxylic acid

KW - Zinc(II) complexes

UR - https://www.scopus.com/pages/publications/0035952247

U2 - 10.1016/S0020-1693(00)00361-3

DO - 10.1016/S0020-1693(00)00361-3

M3 - Article

AN - SCOPUS:0035952247

SN - 0020-1693

VL - 313

SP - 95

EP - 99

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

Syntheses and crystal structures of zinc(II) complexes with three kinds of piperidine carboxylic acids

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Keywords

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