Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique

Jitladda Sakdapipanich; Tippawan Kowitteerawut; Kawahara Seiichi; Yasuyuki Tanaka

doi:10.1007/s002890170035

Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique

Jitladda Sakdapipanich
, Tippawan Kowitteerawut
, Kawahara Seiichi
, Yasuyuki Tanaka

Mahidol University
Nagaoka University of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Commercial highly cis-1,4-polybutadiene was cured out by benzoyl peroxide from 3 to 12 phr in toluene solution. The structural characterization of resulting gel fraction or cured rubber was carried out in both swollen- and solid-state ¹³C-NMR measurements. The assignment of observed chemical shift proposed by using a shift factor method and empirical calculation using HOSE method.

Original language	English
Pages (from-to)	479-485
Number of pages	7
Journal	Polymer Bulletin
Volume	46
Issue number	6
DOIs	https://doi.org/10.1007/s002890170035
Publication status	Published - 2001
Externally published	Yes

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10.1007/s002890170035

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title = "Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique",

abstract = "Commercial highly cis-1,4-polybutadiene was cured out by benzoyl peroxide from 3 to 12 phr in toluene solution. The structural characterization of resulting gel fraction or cured rubber was carried out in both swollen- and solid-state 13C-NMR measurements. The assignment of observed chemical shift proposed by using a shift factor method and empirical calculation using HOSE method.",

author = "Jitladda Sakdapipanich and Tippawan Kowitteerawut and Kawahara Seiichi and Yasuyuki Tanaka",

year = "2001",

doi = "10.1007/s002890170035",

language = "English",

volume = "46",

pages = "479--485",

journal = "Polymer Bulletin",

issn = "0170-0839",

publisher = "Springer Verlag",

number = "6",

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TY - JOUR

T1 - Structural characterization of highly cis-1,4-polybutadiene

T2 - A comparing study in swollen and solid state using NMR technique

AU - Sakdapipanich, Jitladda

AU - Kowitteerawut, Tippawan

AU - Seiichi, Kawahara

AU - Tanaka, Yasuyuki

PY - 2001

Y1 - 2001

N2 - Commercial highly cis-1,4-polybutadiene was cured out by benzoyl peroxide from 3 to 12 phr in toluene solution. The structural characterization of resulting gel fraction or cured rubber was carried out in both swollen- and solid-state 13C-NMR measurements. The assignment of observed chemical shift proposed by using a shift factor method and empirical calculation using HOSE method.

AB - Commercial highly cis-1,4-polybutadiene was cured out by benzoyl peroxide from 3 to 12 phr in toluene solution. The structural characterization of resulting gel fraction or cured rubber was carried out in both swollen- and solid-state 13C-NMR measurements. The assignment of observed chemical shift proposed by using a shift factor method and empirical calculation using HOSE method.

UR - https://www.scopus.com/pages/publications/0034886830

U2 - 10.1007/s002890170035

DO - 10.1007/s002890170035

M3 - Article

AN - SCOPUS:0034886830

SN - 0170-0839

VL - 46

SP - 479

EP - 485

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 6

ER -

Structural characterization of highly cis-1,4-polybutadiene: A comparing study in swollen and solid state using NMR technique

Abstract

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