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Preparation of nanocomposite chitosan/silk fibroin blend films containing nanopore structures

  • Faculty of Science
  • Mahidol University
  • Mahidol University

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

Chitosan (CS)/silk fibroin (SF) blend films containing nanoparticles of methoxy poly(ethylene glycol)-b-poly(d,l-lactide) (MPEG-b-PDLL) were prepared by film casting of nanoparticle suspension-CS/SF blend solution. The nanocomposite blend films with CS/SF blend ratios of 2/0, 2/1, 2/2, 1/2 and 0/2 (w/w) were investigated. FTIR results showed the intermolecular bonds existed between nanoparticles and CS/SF film matrices. The nanoparticles with spherical shape observed from SEM micrographs were approximately less than 1 μm in size and dispersed throughout the film matrices. Nanopores on both film surfaces and cross-sections of the nanocomposite blend films were formed due to self-condensation and phase separation of the nanoparticles. The nanocomposite blend films contained nanoparticles exhibited an increase of film strength and decrease of film flexibility and water wettability.

Original languageEnglish
Pages (from-to)60-65
Number of pages6
JournalCarbohydrate Polymers
Volume78
Issue number1
DOIs
Publication statusPublished - 4 Aug 2009

Keywords

  • Blend films
  • Chitosan
  • Nanocomposite films
  • Nanoporous structures
  • Silk fibroin

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