Post-synthetic modification of conjugated microporous polymers

Thanchanok Ratvijitvech; Robert Dawson; Andrea Laybourn; Yaroslav Z. Khimyak; Dave J. Adams; Andrew I. Cooper

doi:10.1016/j.polymer.2013.06.004

Post-synthetic modification of conjugated microporous polymers

Thanchanok Ratvijitvech
, Robert Dawson
, Andrea Laybourn
, Yaroslav Z. Khimyak
, Dave J. Adams
, Andrew I. Cooper

University of Liverpool
University of East Anglia

Research output: Contribution to journal › Article › peer-review

121 Citations (Scopus)

Abstract

Control over the surface functionality and microporosity in conjugated microporous polymers (CMPs) has been achieved by the post-synthetic modification of amines into amides of with different alkyl chains, one of which was chiral. The surface areas, pore volumes, carbon dioxide uptakes and isosteric heat of adsorption for carbon dioxide can be rationally tuned.

Original language	English
Pages (from-to)	321-325
Number of pages	5
Journal	Polymer
Volume	55
Issue number	1
DOIs	https://doi.org/10.1016/j.polymer.2013.06.004
Publication status	Published - 14 Jan 2014
Externally published	Yes

Keywords

Conjugated polymer
Microporous
Polymer synthesis

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10.1016/j.polymer.2013.06.004

Cite this

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abstract = "Control over the surface functionality and microporosity in conjugated microporous polymers (CMPs) has been achieved by the post-synthetic modification of amines into amides of with different alkyl chains, one of which was chiral. The surface areas, pore volumes, carbon dioxide uptakes and isosteric heat of adsorption for carbon dioxide can be rationally tuned.",

keywords = "Conjugated polymer, Microporous, Polymer synthesis",

author = "Thanchanok Ratvijitvech and Robert Dawson and Andrea Laybourn and Khimyak, \{Yaroslav Z.\} and Adams, \{Dave J.\} and Cooper, \{Andrew I.\}",

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AU - Ratvijitvech, Thanchanok

AU - Dawson, Robert

AU - Laybourn, Andrea

AU - Khimyak, Yaroslav Z.

AU - Adams, Dave J.

AU - Cooper, Andrew I.

PY - 2014/1/14

Y1 - 2014/1/14

N2 - Control over the surface functionality and microporosity in conjugated microporous polymers (CMPs) has been achieved by the post-synthetic modification of amines into amides of with different alkyl chains, one of which was chiral. The surface areas, pore volumes, carbon dioxide uptakes and isosteric heat of adsorption for carbon dioxide can be rationally tuned.

AB - Control over the surface functionality and microporosity in conjugated microporous polymers (CMPs) has been achieved by the post-synthetic modification of amines into amides of with different alkyl chains, one of which was chiral. The surface areas, pore volumes, carbon dioxide uptakes and isosteric heat of adsorption for carbon dioxide can be rationally tuned.

KW - Conjugated polymer

KW - Microporous

KW - Polymer synthesis

UR - https://www.scopus.com/pages/publications/84891828164

U2 - 10.1016/j.polymer.2013.06.004

DO - 10.1016/j.polymer.2013.06.004

M3 - Article

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SN - 0032-3861

VL - 55

SP - 321

EP - 325

JO - Polymer

JF - Polymer

IS - 1

ER -

Post-synthetic modification of conjugated microporous polymers

Abstract

Keywords

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