Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite: Synthesis of α-Nitrooximes

Napasawan Chumnanvej; Praewpan Katrun; Manat Pohmakotr; Vichai Reutrakul; Darunee Soorukram; Chutima Kuhakarn

doi:10.1002/cjoc.201600167

Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite: Synthesis of α-Nitrooximes

Napasawan Chumnanvej
, Praewpan Katrun
, Manat Pohmakotr
, Vichai Reutrakul
, Darunee Soorukram
, Chutima Kuhakarn

Mahidol University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite (t-BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α-nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal-free reagent, environmentally benign solvent and simple experimental procedure.

Original language	English
Pages (from-to)	830-838
Number of pages	9
Journal	Chinese Journal of Chemistry
Volume	34
Issue number	8
DOIs	https://doi.org/10.1002/cjoc.201600167
Publication status	Published - Aug 2016
Externally published	Yes

Keywords

nitration-oximization
styrenes
tert-butyl nitrite
α-nitrooximes

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10.1002/cjoc.201600167

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title = "Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite: Synthesis of α-Nitrooximes",

abstract = "A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite (t-BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α-nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal-free reagent, environmentally benign solvent and simple experimental procedure.",

keywords = "nitration-oximization, styrenes, tert-butyl nitrite, α-nitrooximes",

author = "Napasawan Chumnanvej and Praewpan Katrun and Manat Pohmakotr and Vichai Reutrakul and Darunee Soorukram and Chutima Kuhakarn",

note = "Publisher Copyright: Copyright {\textcopyright} 2016 SIOC, CAS, Shanghai \& WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2016",

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T2 - Synthesis of α-Nitrooximes

AU - Chumnanvej, Napasawan

AU - Katrun, Praewpan

AU - Pohmakotr, Manat

AU - Reutrakul, Vichai

AU - Soorukram, Darunee

AU - Kuhakarn, Chutima

PY - 2016/8

Y1 - 2016/8

N2 - A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite (t-BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α-nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal-free reagent, environmentally benign solvent and simple experimental procedure.

AB - A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite (t-BuONO) in DMSO was developed. The present method offers a convenient and practical approach for the synthesis of α-nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal-free reagent, environmentally benign solvent and simple experimental procedure.

KW - nitration-oximization

KW - styrenes

KW - tert-butyl nitrite

KW - α-nitrooximes

UR - https://www.scopus.com/pages/publications/84964426949

U2 - 10.1002/cjoc.201600167

DO - 10.1002/cjoc.201600167

M3 - Article

AN - SCOPUS:84964426949

SN - 1001-604X

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JF - Chinese Journal of Chemistry

IS - 8

ER -

Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite: Synthesis of α-Nitrooximes

Abstract

Keywords

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