Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

Manat Pohmakotr; Sirinporn Thamapipol; Patoomratana Tuchinda; Samran Prabpai; Palangpon Kongsaeree; Vichai Reutrakul

doi:10.1021/jo0705566

Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

Manat Pohmakotr
, Sirinporn Thamapipol
, Patoomratana Tuchinda
, Samran Prabpai
, Palangpon Kongsaeree
, Vichai Reutrakul

Mahidol University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

(Chemical Equation Presented) The reaction of masked 5-alkylidene-2- cyclopentenones with aldehydes catalyzed by tributylphosphine in the presence of phenol provided the corresponding Morita-Baylis-Hillman adducts, which were subjected to flash vacuum pyrolysis to afford 5-alkylidene-2-(hydroxyalkyl)-2- cyclopentenones.

Original language	English
Pages (from-to)	5418-5420
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	72
Issue number	14
DOIs	https://doi.org/10.1021/jo0705566
Publication status	Published - 6 Jul 2007
Externally published	Yes

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10.1021/jo0705566

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title = "Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones",

abstract = "(Chemical Equation Presented) The reaction of masked 5-alkylidene-2- cyclopentenones with aldehydes catalyzed by tributylphosphine in the presence of phenol provided the corresponding Morita-Baylis-Hillman adducts, which were subjected to flash vacuum pyrolysis to afford 5-alkylidene-2-(hydroxyalkyl)-2- cyclopentenones.",

author = "Manat Pohmakotr and Sirinporn Thamapipol and Patoomratana Tuchinda and Samran Prabpai and Palangpon Kongsaeree and Vichai Reutrakul",

year = "2007",

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doi = "10.1021/jo0705566",

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volume = "72",

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T1 - Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones

T2 - General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

AU - Pohmakotr, Manat

AU - Thamapipol, Sirinporn

AU - Tuchinda, Patoomratana

AU - Prabpai, Samran

AU - Kongsaeree, Palangpon

AU - Reutrakul, Vichai

PY - 2007/7/6

Y1 - 2007/7/6

N2 - (Chemical Equation Presented) The reaction of masked 5-alkylidene-2- cyclopentenones with aldehydes catalyzed by tributylphosphine in the presence of phenol provided the corresponding Morita-Baylis-Hillman adducts, which were subjected to flash vacuum pyrolysis to afford 5-alkylidene-2-(hydroxyalkyl)-2- cyclopentenones.

AB - (Chemical Equation Presented) The reaction of masked 5-alkylidene-2- cyclopentenones with aldehydes catalyzed by tributylphosphine in the presence of phenol provided the corresponding Morita-Baylis-Hillman adducts, which were subjected to flash vacuum pyrolysis to afford 5-alkylidene-2-(hydroxyalkyl)-2- cyclopentenones.

UR - https://www.scopus.com/pages/publications/34447334803

U2 - 10.1021/jo0705566

DO - 10.1021/jo0705566

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SN - 0022-3263

VL - 72

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 14

ER -

Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

Abstract

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