无溶剂热处理固相转化法简易制备沸石咪唑酯骨架材料

Wei Xu; Jichao Wang; Guangyong Shi; Chaemchuen Somboon

doi:10.7503/cjcu20200010

无溶剂热处理固相转化法简易制备沸石咪唑酯骨架材料

Translated title of the contribution: Facile Preparation of Zeolitic Imidazole Frameworks by Thermal Treatment Solid-Phase Transformation

Wei Xu
, Jichao Wang
, Guangyong Shi
, Chaemchuen Somboon

Wuhan University of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The facile synthesis of zeolitic imidazolate frameworks(H-ZIF-67) under fully avoided solvent and a short reaction was achieved. The solid-phase transformation of mixed metal and organic ligand sources during the heat treatment process was a crucial mechanism of synthesis strategy. The synthesized materials were characterized by means of powder-XRD, SEM, TEM, TGA, FTIR, porosity, and N₂ adsorption-desorption analyses. The results illustrate the characteristic properties compatibility with the commercial methods for the preparation of ZIF-67 have been reported. The single-step, truly solvent-free, non-post treatment, short-time synthesis, and safety system as ambient pressure, were an advantage of this developed method.

Translated title of the contribution	Facile Preparation of Zeolitic Imidazole Frameworks by Thermal Treatment Solid-Phase Transformation
Original language	Chinese (Traditional)
Pages (from-to)	1753-1759
Number of pages	7
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	41
Issue number	8
DOIs	https://doi.org/10.7503/cjcu20200010
Publication status	Published - 10 Aug 2020
Externally published	Yes

Keywords

Heat treatment
Solid phase transformation
Solvent-free synthesis
Zeolite imidazolate framework material

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10.7503/cjcu20200010

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title = "无溶剂热处理固相转化法简易制备沸石咪唑酯骨架材料",

abstract = "The facile synthesis of zeolitic imidazolate frameworks(H-ZIF-67) under fully avoided solvent and a short reaction was achieved. The solid-phase transformation of mixed metal and organic ligand sources during the heat treatment process was a crucial mechanism of synthesis strategy. The synthesized materials were characterized by means of powder-XRD, SEM, TEM, TGA, FTIR, porosity, and N2 adsorption-desorption analyses. The results illustrate the characteristic properties compatibility with the commercial methods for the preparation of ZIF-67 have been reported. The single-step, truly solvent-free, non-post treatment, short-time synthesis, and safety system as ambient pressure, were an advantage of this developed method.",

keywords = "Heat treatment, Solid phase transformation, Solvent-free synthesis, Zeolite imidazolate framework material",

author = "Wei Xu and Jichao Wang and Guangyong Shi and Chaemchuen Somboon",

year = "2020",

month = aug,

day = "10",

doi = "10.7503/cjcu20200010",

language = "Chinese (Traditional)",

volume = "41",

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TY - JOUR

T1 - 无溶剂热处理固相转化法简易制备沸石咪唑酯骨架材料

AU - Xu, Wei

AU - Wang, Jichao

AU - Shi, Guangyong

AU - Somboon, Chaemchuen

PY - 2020/8/10

Y1 - 2020/8/10

N2 - The facile synthesis of zeolitic imidazolate frameworks(H-ZIF-67) under fully avoided solvent and a short reaction was achieved. The solid-phase transformation of mixed metal and organic ligand sources during the heat treatment process was a crucial mechanism of synthesis strategy. The synthesized materials were characterized by means of powder-XRD, SEM, TEM, TGA, FTIR, porosity, and N2 adsorption-desorption analyses. The results illustrate the characteristic properties compatibility with the commercial methods for the preparation of ZIF-67 have been reported. The single-step, truly solvent-free, non-post treatment, short-time synthesis, and safety system as ambient pressure, were an advantage of this developed method.

AB - The facile synthesis of zeolitic imidazolate frameworks(H-ZIF-67) under fully avoided solvent and a short reaction was achieved. The solid-phase transformation of mixed metal and organic ligand sources during the heat treatment process was a crucial mechanism of synthesis strategy. The synthesized materials were characterized by means of powder-XRD, SEM, TEM, TGA, FTIR, porosity, and N2 adsorption-desorption analyses. The results illustrate the characteristic properties compatibility with the commercial methods for the preparation of ZIF-67 have been reported. The single-step, truly solvent-free, non-post treatment, short-time synthesis, and safety system as ambient pressure, were an advantage of this developed method.

KW - Heat treatment

KW - Solid phase transformation

KW - Solvent-free synthesis

KW - Zeolite imidazolate framework material

UR - https://www.scopus.com/pages/publications/85092384909

U2 - 10.7503/cjcu20200010

DO - 10.7503/cjcu20200010

M3 - Article

AN - SCOPUS:85092384909

SN - 0251-0790

VL - 41

SP - 1753

EP - 1759

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 8

ER -

无溶剂热处理固相转化法简易制备沸石咪唑酯骨架材料

Abstract

Keywords

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